Use of Mass Spectrometric Vapor Analysis To Improve Canine Explosive Detection Efficiency
Ta-Hsuan Ong*, Ted Mendum, Geoff Geurtsen, Jude Kelley, Alla Ostrinskaya, Roderick Kunz
Canines remain the gold standard for explosives detection in many situations, and there is an ongoing desire for them to perform at the highest level. This goal requires canine training to be approached similarly to scientific sensor design. A sensitive, real-time (∼1 s) vapor analysis mass spectrometer was developed to provide tools, techniques, and knowledge to better understand, train, and utilize canines.
Direct quantification of chemical warfare agents and related compounds at low ppt levels: comparing active capillary DBDI and SESI mass spectrometry
J-C Wolf, M. Schaer, P. Siegenthaler, R. Zenobi
A novel active capillary dielectric barrier discharge plasma ionization (DBDI) technique for mass spectrometry is applied to the direct detection of thirteen chemical warfare related compounds, including sarin, and compared to secondary electrospray ionization (SESI) in terms of selectivity and sensitivity. The investigated compounds include an intact chemical warfare agent and structurally related molecules, hydrolysis products and/or precursors of highly toxic nerve (G-series, V-series and "new" nerve agents), blistering and incapacitating warfare agents. …